Publications

120

Partovi, S.; Losovyj, Y.; Yamamoto, N.; Smith, J.M. "A Dinuclear Nickel Complex for Electrocatalytic Nitrite Reduction" Inorg. Chem. 2025, 64, 6293-6300.

119

Tran, B.G.; Smith, J.M. "Nitrogen Oxyanion Deoxygenation: Redox Chemistry and Oxygen Atom Transfer Reactions" Coord. Chem. Rev. 2025, 530, 216490.

118

Wannipurage, D.C.; Chivington, A.D.; Losovyj, Y.; Pink, M.; Smith, J.M. "Synthesis and Reactivity of a Paramagnetic Iron Phosphaethynolate Complex" Organometallics 2025, 44, 468-471.

117

Wannipurage, D.C.; Yang, E.S.; Chivington, A.D.; Fletcher, J.; Ray, D.; Yamamoto, N.; Pink, M.; Goicoechea, J.M.; Smith, J.M. "A Transient Iron Carbide Generated by Cyaphide Cleavage" J. Am. Chem. Soc. 2024, 146, 27173-27178.

116

Kaul, N.; Asempa, E.; Valdez-Moreira, J.A.; Smith, J.M.; Jakubikova, E.; Hammarström, L. "Enter Mn^IV−NHC: A Dark Photooxidant with a Long-Lived Charge-Transfer Excited State" J. Am. Chem. Soc. 2024, 146, 24619-24629.

115

Ghosh, M.; Ezhov, R.; Braley, S.E.; Losovyj, Y.; Bury, G.; Pushkar, Y.N.; Smith, J.M. "Metal-Dependent Electrocatalytic Oxygen Reduction in Surface-Conjugated Macrocyclic Electrodes" ACS Appl. Energy Mater. 2024, 7, 6717-6726.

114

Chivington, A.D.; Squire, S.; Yamamoto, N.; Pink, M.; Griffith, M.D.; Fletcher, J.; Gao, Y.; Zadrozny, J.M.; Smith, J.M. "Trimethylsilyldiazomethane Disassembly at a Three-Fold Symmetric Iron Site" Inorg. Chem. 2024, 63, 10221-10229.

113

Partovi, S.; Dalton, E.Z.; Smith, J.M. "Buffer-Induced Electrocatalytic Nitrite Reduction: Impact on Catalytic Rate and Product Selectivity" ACS Catal. 2024, 14, 7756-7761.

112

Gao, Y.; Smith, J.M. "Enabling Nucleophilic Reactivity in High-Spin Fe(II) Imido Complexes: From Elementary Steps to Cooperative Catalysis" Acc. Chem. Res. 2023, 56, 3392-3403.

111

Richerme, P.; Revelle, M.C.; Yale, C.G.; Lobser, D.; Burch, A.D.; Clark, S.M.; Saha, D.; Lopez-Ruiz, M.A.; Dwivedi, A.; Smith, J.M.; Norrell, S.A.; Sabry, A.; Iyengar, S.S. "Quantum Computation of Hydrogen Bond Dynamics and Vibrational Spectra" J. Phys. Chem. Lett. 2023, 14, 7256-7263.

110

Valdez-Moreira, J.A.; Wannipurage, D.C.; Pink, M.; Carta, V.; Moënne-Loccoz, P.; Telser, J.; Smith, J.M. "Hydrogen Atom Abstraction by a High-Spin [Fe^III=S] Complex" Chem. 2023, 9, 2601–2609.

109

Gao, Y.; Li, X.; Stevens, J.E.; Tang, H.; Smith, J.M. "Catalytic 1,3-Proton Transfer in Alkenes Enabled by Fe═NR Bond Cooperativity: A Strategy for pK_a-Dictated Regioselective Transposition of C═C Double Bonds" J. Am. Chem. Soc. 2023, 145, 11978–11987.

108

Cao, Y.; Valdez-Moreira, J.A.; Hay, S.; Smith, J.M.; de Visser, S.P. "Reactivity Differences of Trigonal Pyramidal Nonheme Iron(IV)-Oxo and Iron(III)-Oxo Complexes: Experiment and Theory" Chem. Eur. J. 2023, 29, e202300271.

107

Gao, Y.; Lee, W.-T..; Carta, V.; Chen, C.-H.; Telser, J.; Smith, J.M.. ""Heteroleptic Square Planar Cobalt(I/II) Complexes" Eur. J. Inorg. Chem. 2023, e202200675

106

Huerfano, I.J.; Laskowsi, C.A.; Pink, M.; Carta, V.; Hillhouse, G.L.; Caulton, K.G.; Smith, J.M. "Redox-Neutral Transformations of Carbon Dioxide Using Coordinatively Unsaturated Late Metal Silyl Amide Complexes" Inorg. Chem. 2022, 61, 20986–20993.

105

Tran, B.G.; Carta, V.; Pink, M.; Caulton, K.G.; Smith, J.M. "Facile Addition of B–H and B–B Bonds to an Iron(IV) Nitride Complex" Inorg. Chem. 2022, 61, 19800-19805.

104

Ghosh, M.; Braley, S.E.; Ezhov, R.; Worster, H.; Valdez-Moreira, J.A.; Losovoyj, Y.; Jakubikova, E.; Pushkar, Y.N.; Smith, J.M. "A Spectroscopically Observed Iron Nitrosyl Intermediate in the Reduction of Nitrate by a Surface-Conjugated Electrocatalyst" J. Am. Chem. Soc. 2022, 144, 17824-17831.

103

Gao, Y.; Pink, M.; Carta, V.; Smith, J.M. "Ene Reactivity of an Fe=NR Bond Enables the Catalytic α-Deuteration of Nitriles and Alkynes" J. Am. Chem. Soc. 2022, 144, 17165-17172.

102

Braley, S.E; Kwon, H.-Y.; Xu, S.; Dalton, E.Z.; Jakubikova, E.; Smith, J.M. "Buffer Assists Electrocatalytic Nitrite Reduction by a Cobalt Macrocycle Complex" Inorg. Chem. 2022, 61, 12998-13006.

101

Partovi, S.; Xiong, Z.; Kulesa, K.M.; Smith, J.M. "Electrocatalytic Reduction of Nitrogen Oxyanions with a Redox-Active Cobalt Macrocycle Complex" Inorg. Chem. 2022, 61, 9034-9039

100

Ghosh, M.; Ibrar, M.; Smith, J.M. "Electrocatalytic Reduction of Nitrate by in-situ Generated Cobalt Nanoparticles" Chem. Commun. 2022, 58, 4783-4786.

99

Gao, Y.; Pink, M.; Smith, J.M. "Alkali Metal Ions Dictate the Structure and Reactivity of an Iron(II) Imido Complex" J. Am. Chem. Soc. 2022, 144, 1789-1794.

98

Saha, D.; Iyengar, S.S.; Richerme, P.; Smith, J.M.; Sabry, A. "Mapping Quantum Chemical Dynamics Problems to Spin-Lattice Simulators" J. Chem. Theory Comput. 2021, 17, 6713-6732.

97

Valdez-Moreira, J.A.; Beagan, D.M.; Yang, H.; Telser, J.; Hoffman, B.M.; Pink, M.; Carta, V.; Smith, J.M. "Hydrocarbon Oxidation by an Exposed, Multiply Bonded Iron(III) Oxo Complex" ACS Cent. Sci. 2021, 7, 1751-1755.

96

Kwon, H.-Y.; Braley, S.E.; Madriaga, J.P.; Smith, J.M.; Jakubikova, E. "Electrocatalytic Nitrate Reduction with Co-based Catalysts: Comparison of DIM, TIM and cyclam Ligands" Dalton Trans. 2021, 50, 12324-12331.

95

Braley, S.E.; Xie, J.; Losovyj, Y.; Smith, J.M. "Graphite Conjugation of a Macrocyclic Cobalt Complex Enhances Nitrite Electroreduction to Ammonia" J. Am. Chem. Soc. 2021, 143, 7203-7208.

94

Gao, Y.; Carta, V.; Pink, M.; Smith, J.M. "Catalytic Carbodiimide Guanylation by a Nucleophilic, High Spin Iron(II) Imido Complex" J. Am. Chem. Soc. 2021, 143, 5324-5329.

93

Gao, Y.; Pink, M.; Smith, J.M. "Iron(II) Complexes of an Anionic Bis(ylide)diphenylborate Ligand" Inorg. Chem. 2020, 59, 17303-17309.

92

Martinez, J.L.; Lutz, S.A.; Yang, H.; Xie, J.; Telser, J.; Hoffman, B.M.; Carta, V.; Pink, M.; Losovyj, Y.; Smith, J.M. "Structural and Spectroscopic Characterization of an Fe(VI) Bis(imido) Complex" Science 2020, 370, 356-359.

91

Martinez, J.L.; Lutz, S.A.; Beagan, D.M.; Gao, X.; Pink, M.; Chen, C.-H.; Carta, V.; Moënne-Loccoz, P.; Smith, J.M. "Stabilization of the Dinitrogen Analogue, Phosphorus Nitride" ACS. Cent. Sci. 2020, 6, 1572-1577.

90

Lutz, S.A.; Hickey, A.K.; Gao, Y.; Chen, C.-H.; Smith, J.M. "Two-State Reactivity in Iron-Catalyzed Alkene Isomerization Confers σ-Base Resistance" J. Am. Chem. Soc. 2020, 142, 15527-15535.

89

Valdez-Moreira, J.A.; Millikan, S.P.; Gao, X.; Carta, V.; Chen, C.-H.; Smith, J.M. "Hydrosilylation of an Iron Nitride Complex" Inorg. Chem. 2020, 59, 579-583.

88

Braley, S.E.; Ashley, D.C.; Kulesa, K.M.; Jakubikova, E.; Smith, J.M. "Electrode Adsorption Activates trans-[Cr(cyclam)Cl₂]⁺ for Electrocatalytic Nitrate Reduction" Chem. Commun. 2020, 56, 603-606.

87

Valdez-Moreira, J.A.; Thorarinsdottir, A.E.; DeGayner, J.A.; Lutz, S.A.; Chen, C.-H.; Losovyj, Y.; Pink, M.; Harris, T.D.; Smith, J.M. "Strong 𝜋-Backbonding Enables Record Magnetic Exchange Coupling Through Cyanide" J. Am. Chem. Soc. 2019, 141, 17902-17097.

86

Hickey, A.K.; Greer, S.M.; Valdez-Moreira, J.A.; Lutz, S.A.; Pink, M.; DeGayner, J.A.; Harris, T.D.; Hill, S.; Telser, J.; Smith, J.M. "A Dimeric Hydride-Bridged Complex with Geometrically Distinct Iron Centers Giving Rise to an S = 3 Ground State" J. Am. Chem. Soc. 2019, 141, 11970-11975.

85

Xu, S.; Kwon, H.-Y.; Ashley, D.C.; Chen, C.-H.; Jakubikova, E.; Smith, J.M. "Intramolecular Hydrogen Bonding Facilitates Electrocatalytic Nitrite Reduction in Aqueous Solutions" Inorg. Chem. 2019, 58, 9443-9451.

84

Ding, M.; Hickey, A.K.; Pink, M.; Telser, J.; Tierney, D.L.; Amoza, M.; Rouzières, M.; Ozumerzifon, T.J.; Hoffert, W.A.; Shores, M.P.; Ruiz, E.; Clérac, R.; Smith, J.M. "Magnetization Slow Dynamics in Ferrocenium Complexes" Chem. Eur. J. 2019, 25, 10625-10623..

83

Martinez, J.L.; Lee, W.-T.; Pink, M.; Chen, C.-H.; Smith, J.M. "Heteroleptic Nickel Complexes of a Bulky Bis(carbene)borate Ligand" Polyhedron 2018, 156, 297-302 (Bill Jones special issue).

82

Crandell, D.W.; Muñoz, III, S.B.; Smith, J.M.; Baik, M-H. "Mechanistic Study of Styrene Aziridination by Iron(IV) Nitrides" Chem. Sci. 2018, 9, 8542-8552.

81

Xu, S.; Ashley, D.C.; Kwon, K.-Y.; Ware, G.R.; Chen, C.-H.; Losovyj, Y.; Gao, X.; Jakubikova, E.; Smith, J.M. "A Flexible, Redox-Active Macrocycle Enables the Electrocatalytic Reduction of Nitrate to Ammonia by a Cobalt Complex" Chem. Sci. 2018, 9, 4950-4958.

80

Xu, S.; Bucinsky, L.; Breza, M.; Krzystek, J.; Chen, C.-H.; Pink, M.; Telser, J.; Smith, J.M. "Ligand Substituent Effects in Manganese Pyridinophane Complexes: Implications for Oxygen-Evolving Catalysis" Inorg. Chem. 2017, 56, 14315-14325.

79

Martinez, J.L.; Lin, H.-J.; Lee, W.-T.; Pink, M.; Chen, C.-H.; Gao, X.; Dickie, D.A.; Smith, J.M. "Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride" J. Am. Chem. Soc. 2017, 139, 14037-14040.

78

Bucinsky, L.; Breza, M.; Lee, W.-T.; Hickey, A.K.; Dickie, D.A.; Nieto, I.; DeGayner, J.A.; Harris, T.D.; Meyer, K.; Krzystek, J.; Ozarowski, A.; Nehrkorn, J.; Schnegg, A.; Holldack, K.; Herber, R.H.; Telser, J.; Smith, J.M. "Spectroscopic and Computational Studies of Spin States of Iron(IV) Imido and Nitrido Complexes" Inorg. Chem. 2017, 56, 4751-4768.

77

Crandell, D.; Xu, S.; Smith, J.M.; Baik, M.-H. "Intramolecular Oxyl Radical Coupling Promotes O–O Bond Formation in a Homogeneous Mononuclear Mn-based Water Oxidation Catalyst: A Computational Mechanistic Investigation" Inorg. Chem. 2017, 56, 4436-4446.

76

Baslon, V.; Harris, J.P.; Reber, C.; Colmer, H.E.; Jackson, T.A.; Forshaw, A.P.; Kinney, R.A.; Telser, J. "Near-infrared ²E_g → ⁴A_2g and visible LMCT luminescence from a molecular bis- (tris(carbene)borate) manganese(IV) complex" Can. J. Chem. 2017, 95, 547-552.

75

Hickey, A.K.; Lutz, S.A.; Chen, C.-H.; Smith, J.M. "Two-State Reactivity in C-H Activation by a Four-Coordinate Iron(0) Complex" Chem. Commun. 2017, 53, 1245-1248.

74

Hickey, A.K.; Muñoz, III, S.B.; Lutz, S.A.; Pink, M.; Chen, C.-H.; Smith, J.M. "Arrested α-Hydride Migration Activates a Phosphido Ligand for C-H Insertion" Chem. Commun. 2017, 53, 412-415.

73

Hickey, A.K.; Lee, W.-T.; Chen, C.-H.; Pink, M.; Smith, J.M. "A Bidentate Ligand Stabilizes a Low-Coordinate Iron(0) Carbonyl Complex" Organometallics 2016, 35, 3069-3073.

72

Ding, M.; Aravena, D.; Amoza, M.; Cutsail, III, G.E.;Rouzières, M.; Dechambenoit, P.; Losovyj, Y.; Pink, M.; Ruiz, E.; Clérac, R.; Smith, J.M. "A Low Spin Manganese(IV) Nitride Single Molecule Magnet" Chem. Sci. 2016, 7, 6132-6140.

71

Colmer, H.E.; Margarit, C.G.; Smith, J.M.; Jackson, T.A.; Telser, J. "Spectroscopic and Computational spectroscopy and Investigation of Low-Spin Mn^III Bis(scorpionate) Complexes" Eur. J. Inorg. Chem. 2016, 2143-2423.

70

Hickey, A.K.; Chen, C.-H.; Pink, M.; Smith, J.M. "Low-Valent Iron Carbonyl Complexes with a Tripodal Carbene Ligand" Organometallics 2015, 34, 4560-4566.

69

Ding, M.; Rouzières, M.; Losovyj, Y.; Pink, M.; Clérac, R.; Smith, J.M. "Partial Nitrogen Atom Transfer: a New Synthetic Tool to Design Single-Molecule Magnets" Inorg. Chem. 2015, 54, 9075-9080.

68

Muñoz, III, S.B.; Lee, W.-T.; Dickie, D.A.; Scepaniak, J.J.; Subedi, D.; Pink, M.; Johnson, M.D.; Smith, J.M. "Styrene Aziridination by Iron(IV) Nitrides" Angew. Chem. Int. Ed. 2015, 54, 10600-10603.

67

Lin, H-.J.; Siretanu, D.; Dickie, D.A.; Subedi, D.; Scepaniak, J.J.; Mitcov, D.; Clérac, R.; Smith, J.M. "Steric and Electronic Control of the Spin State in Three-Fold Symmetric, Four-Coordinate Iron(II) Complexes" J. Am. Chem. Soc. 2014, 136, 13326-13332.

66

Juarez, R.A.; Lee, W.-T.; Smith, J.M.; Wang, H. "Computational Evaluation of Tris(carbene)borate Donor Properties in {NiNO}¹⁰ Complexes" Dalton Trans., 2014, 43, 14689-14695.

65

Cutsail, G.E. III; Stein, B.W.; Subedi, D.; Smith, J.M.; Kirk, M.L.; Hoffman, B.M. "EPR, ENDOR and Electronic Structure Studies of the Jahn-Teller Distortion in an Fe^V Nitride" J. Am. Chem. Soc., 2014, 136, 12323-12336.

64

Lee, W.-T.; Muñoz, S.B. III; Dickie, D.A.; Smith, J.M. "Ligand Modification Transforms a Catalase Mimic into a Water Oxidation Catalyst" Angew. Chem., Int. Ed., 2014, 53, 9856-9859.

63

Lee, W.-T.; Jeon, I.-R.; Xu, S.; Dickie, D.A.; Smith, J.M. "Low-Coordinate Iron(II) Complexes of a Bulky Bis(carbene)borate Ligand" Organometallics, 2014, 33, 5654-5659 (invited contribution to a special issue on earth abundant metals).

62

Lee, W.-T.; Juarez, R.A.; Scepaniak, J.J.; Muñoz, S.B; Dickie, D.A.; Wang, H.; Smith, J.M. "Reaction of an Iron(IV) Nitrido Complex with Cyclohexadienes: Cycloaddition and Hydrogen Atom Abstraction" Inorg. Chem., 2014, 53, 8425-8430.

61

Smith, J.M. "Reactive Transition Metal Nitride Complexes" Progress Inorg. Chem. 2014, 58, 417-470 (invited review).

60

Mathonière, C.; Lin, H.-J.; Siretanu, D.; Clérac, R.; Smith, J.M. "Photoinduced Single-Molecule Magnet Properties in a Four-Coordinate Iron(II) Spin Crossover Complex" J. Am. Chem. Soc. 2013, 135, 19083-19086.

59

Lee, W.-T.; Dickie, D.A.; Metta-Magaña, A.; Smith, J.M. "A Tripodal Ligand Constructed from Mesoionic Carbene Donors" Inorg. Chem. 2013, 52, 12842-12846.

58

Scepaniak, J.J.; Margarit, C.G.; Bontchev, R.P.; Smith, J.M. "Cobalt Azide Complexes with a Tris(carbene)borate Ligand Scaffold" Acta Cryst. 2013, C69, 968-971 (invited contribution for a special issue on scorpionate ligands).

57

Lee, W.-T.; Xu, S.; Dickie, D.A.; Smith, J.M. "A Robust Mn Catalyst for H2O2 Disproportionation in Aqueous Solution" Eur. J. Inorg. Chem. 2013, 3867-3873 (invited contribution for a cluster issue on small molecule activation).

56

Forshaw, A.P.; Smith, J.M.; Ozarowski, A.; Krzystek, J.; Smirnov, D.; Zvyagin, S.A.; Harris, T.D.; Kuranadasa, H.I.; Zadrozny, J.M.; Schnegg, A.; Holldack, K.; Jackson, T.A; Alamiri, A.; Barnes, D.M.; Telser, J. "Low-Spin Hexa-Coordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes" Inorg. Chem. 2013, 52, 144-159.

55

Smith, J.M.; Mayberry, D.E.; Margarit, C.G.; Sutter, J.; Wang, H.; Meyer, K.; Bontchev, R.P. "N–O Bond Homolysis of an Iron(II) TEMPO Complex to Yield an Iron(III) Oxo" J. Am. Chem. Soc. 2012, 134, 6516-6519.

54

Muñoz, S.B. III; Foster, W.K.; Lin, H.-J.; Margarit, C.G.; Dickie, D.A.; Smith, J.M. "Tris(carbene)borate Ligands featuring Imidazole-2-ylidene, Benzimidazol-2-ylidene and 1,3,4-Triazol-2-ylidene donors. Evaluation of Donor properties in Four-coordinate {NiNO}10 Complexes" Inorg. Chem. 2012, 51, 12660-12668.

53

Smith, J.M.; Subedi, D. "The Structure and Reactivity of Iron Nitride Complexes" Dalton Trans. 2012, 41, 1423-1429 (invited contribution).

52

Scepaniak, J.J.; Margarit, C.G.; Harvey, J.N.; Smith, J.M. "Nitrogen Atom Transfer from Iron(IV) Nitrido Complexes. A Dual-Nature Transition State for Nitrogen Atom Transfer" Inorg. Chem. 2011, 50, 9508-9517.

51

Scepaniak, J.J.; Bontchev, R.P.; Johnson, D.L.; Smith, J.M. "Snapshots of Complete Nitrogen Atom Transfer from an Iron(IV) Nitrido Complex." Angew. Chem. Int. Ed. 2011, 50,6630-6633.

50

Scepaniak, J.J.; Harris, T.D.; Vogel, C.S.; Sutter, J.; Meyer, K.; Smith, J.M. "Spin Crossover in a Four-Coordinate Iron(II) Complex" J. Am. Chem. Soc. 2011, 133, 3824-3827.

49

Scepaniak, J.J.; Vogel, C.S.; Khusniyarov, M.M.; Heinemann, F.W.; Meyer, K.; Smith, J.M. "Synthesis, Structure, and Reactivity of an Iron(V) Nitride" Science 2011, 331, 1049-1052.

48

Smith, J.M.; Long, J.R. "First-Row Transition Metal Complexes of the Strongly Donating Pentadentate Ligand PY4Im" Inorg. Chem. 2010, 49, 11223-11230.

47

Nieto, I.; Bontchev, R.P.; Ozarowski, A.; Smirnov, D.; Krzystek, J.; Telser, J.; Smith, J.M. "Synthesis and Spectroscopic Investigations of Four-Coordinate Nickel Complexes Supported by a Strongly Donating Scorpionate Ligand" Inorg. Chim. Acta 2009, 362, 4449-4460 (invited contribution in honor of Jerry Trofimenko).

46

Scepaniak, J.J.; Young, J.A; Bontchev, R.P.; Smith, J.M. "Formation of Ammonia from an Iron Nitrido Complex" Angew. Chem. Int. Ed. 2009, 48, 3158-3160.

45

Ding, F.; Smith, J.M.; Wang, H. "First-Principles DFT Calculation of pKa's for Organic Acids in Non-Aqueous Solution" J. Org. Chem. 2009, 74, 2679-2691.

44

Smith, J.M. "Strongly Donating Scorpionates" Comments Inorg. Chem. 2008, 29, 189-233.

43

Scepaniak, J.J.; Fulton, M.D.; Bontchev, R.P.; Duesler, E.N.; Kirk, M.L.; Smith, J.M. "Structural and Spectroscopic Characterization of an Electrophilic Iron Nitrido Complex" J. Am. Chem. Soc. 2008, 130, 10515-10517.

42

Nieto, I.; Bontchev, R.P.; Smith, J.M. "Synthesis of a bulky bis(carbene)borate ligand. Contrasting structures of homoleptic nickel(II) bis(pyrazoyl)borate and bis(carbene)borate complexes." Eur. J. Inorg. Chem., 2008, 2476-2480.

41

Nieto, I.; Ding, F.; Bontchev, R.P.; Wang, H.; Smith, J.M. "Thermodynamics of Hydrogen Atom Transfer to a High Valent Iron Imido Complex" J. Am. Chem. Soc. 2008, 130, 2716-2717.

40

Forshaw, A.P.; Bontchev, R.P.; Smith, J.M. "Oxidation of the Tris(carbene)borate Complex PhB(MeIm)₃MnI(CO)₃ to Mn^IV[PhB(MeIm)₃]₂(OTf)₂" Inorg. Chem., 2007, 46, 3792-3794.

39

Cowley, R.E.; Bontchev, R.P.; Sorrell, J.; Sarracino, O.; Feng, Y.; Wang; H.; Smith; J.M. "Formation of a Cobalt(III) Imido from a Cobalt(II) Amido Complex. Evidence for Proton-Coupled Electron Transfer" J. Am. Chem. Soc., 2007, 129, 2424-2425.

38

Cowley, R.E.; Bontchev, R.P.; Duesler, E.N.; Smith, J.M. "Removing the Sting from the Tail. Reversible Protonation of Scorpionate Ligands in Cobalt(II) Tris(carbene)borate Complexes" Inorg. Chem., 2006, 45, 9771-9779.

37

Nieto, I.; Cervantes-Lee, F. Smith, J.M. "A New Synthetic Route to Bulky 'Second Generation' Tris(imidazol-2-ylidene)borates: Synthesis of a Four-Coordinate Iron(II) Complex", Chem. Commun., 2005, 3811-3813.

36

Chiang, K.P.; Barrett, P.M.; Ding, F.; Smith, J.M.; Kingsley, S.; Brennessel, W.W.; Clark, M.M. Lachicotte, R.J.; Holland, P.L. “Ligand Dependence of Binding to Three-Coordinate Fe(II) Complexes” Inorg. Chem. 2009, 48, 5106-5116.

35

Stoian, S.A.; Smith, J.M.; Holland, P.L.; Münck, E.; Bominaar, E.L. “Mössbauer, EPR and theoretical study of a high-spin, four-coordinate Fe(II) diketiminate complex” Inorg. Chem. 2008, 47, 8687-8695.

34

Yu, Y.; Sadique, A.R.; Smith, J.M.; Dugan, T.R.; Cowley, R.E.; Brennessel, W.W.; Flaschenriem, C.J.; Bill, E.; Cundari, T.R.; Holland, P.L. “The Reactivity Patterns of Low-Coordinate Iron Hydride Complexes” J. Am. Chem. Soc. 2008, 130, 6624-6638.

33

Vela, J.; Cirera, J.; Smith, J.M.; Lachicotte, R.J.; Flaschenriem, C.J.; Alvarez, S.; Holland, P.L. “Quantitative Geometric Descriptions of the Belt Iron Atoms of the Iron-Molybdenum Cofactor of Nitrogenase and Synthetic Iron(II) Model Complexes” Inorg. Chem., 2007, 46, 60-71.

32

Stoian, S.; Vela, J.; Smith, J.M.; Holland, P.L.; Münck, E.; Bominaar, E.L. “Mössbauer and Computational Study of an N2-Bridged Diiron(I) Diketiminate Complex: Parallel Alignment of the Iron Spins by Direct Antiferromagnetic Exchange with Activated Dinitrogen” J. Am. Chem. Soc., 2006, 128, 10181-10192.

31

Bourgeois, C.J.; Garratt, S.A.; Hughes, R.P.; Laritchev, R.B.; Smith, J.M.; Ward, A.J.; Zhang, D.; Zakharov, L.N.; Rheingold, A.L. “Synthesis and Structural Characterization of Perfluoroalkyl(fluoro)iridium(III) and Perfluoroalkyl(methyl)iridium(III) Compounds” Organometallics, 2006, 25, 3474-3480.

30

Yu, Y.; Smith, J.M.; Flaschenriem, C.J.; Holland, P.L “Binding Affinity of Unsaturated Ligands in Low-Coordinate Iron(I) Complexes” Inorg. Chem., 2006, 45, 5742-5751. (featured on the July 24, 2006 cover of Inorg. Chem.)

29

Smith, J.M.; Sadique, A.R.; Cundari, T.R.; Rodgers, K.R.; Lukat-Rodgers, G.; Lachicotte, R.J.; Flaschenriem, C.J.; Vela, J; Holland, P.L. “Studies of Low-Coordinate Iron-Dinitrogen Complexes”, J. Am. Chem Soc., 2006, 128, 756-769.

28

Bourgeois, C.J.; Hughes, R.P.; Husebo, T.L.; Smith, J.M.; Guzei, I.M.; Liable-Sands, L.M.; Zakharov, L.N.; Rheingold, A.L. “Reactions of Perfluoroalkyl Iodides with M(C5H5)(CO)(PMe3) [M = Rh, Ir]; Evidence for Direct Fluoroalkylation at a CO Ligand”, Organometallics, 2005, 24, 6431-6439.

27

Eckert, N.A.; Stoian, S.; Smith, J.M.; Lachicotte, R.J.; Münck, E.; Holland, P.L.; “Synthesis, Structure, and Spectroscopy of an Oxodiiron(II) Complex.”, J. Am. Chem. Soc., 2005, 127, 9344-9345.

26

Stoian, S.; Smith, J.M.; Yu, Y.; Bominaar, E.L.; Holland, P.L.; Münck, E. “Mössbauer, EPR and Crystallographic Characterization of a High-spin Fe(I) Diketiminate Complex with Orbital Degeneracy”, Inorg. Chem., 2005, 44, 4915-4922.

25

Vela, J.; Smith, J.M.; Yu, Y.; Ketterer, N.A.; Flaschenriem, C.J.; Lachicotte, R.J.; Holland, P.L. “Synthesis and Reactivity of Low Coordinate Iron(II) Fluorides, and Their Use in the Catalytic Hydrodefluorination of Fluorocarbons”, J. Am. Chem. Soc., 2005, 127, 7857-7870.

24

Vela, J.; Vaddadi, S.; Cundari, T.R.; Smith, J.M.; Gregory, E.A.; Lachicotte, R.J.; Flaschenriem, C.J.; Holland, P.L. “Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies.”, Organometallics 2004, 23, 5226-5239.

23

Eckert, N.A.; Smith, J.M.; Lachicotte, R.J.; Holland, P.L. “Low-Coordinate Fe(II) Amido Complexes of b-Diketiminates: Synthesis, Structure and Reactivity.”, Inorg. Chem., 2004, 43, 3306-3321.

22

Smith, J.M.; Lachicotte, R.J.; Holland, P.L. “N=N Bond Cleavage by a Low Coordinate Iron(II) Hydride Complex.”, J. Am. Chem. Soc., 2003, 125, 15752-15753.

21

Vela, J.; Smith, J.M.; Lachicotte, R.J.; Holland, P.L. “Alkyl Isomerisation in Three-Coordinate Iron(II) Complexes.”, Chem. Commun., 2002, 2886-2887.

20

Pelczar, E.M.; Nytko, E.A.; Zhuravel, M.; Smith, J.M.; Glueck, D.S. “Synthesis and Structure of Platinum and Palladium Complexes of Dimesitylphosphine.”, Polyhedron, 2002, 21, 2409-2419.

19

Smith, J.M.; Lachicotte, R.J.; Holland, P.L. “Three-Coordinate, 12-Electron Organometallic Complexes of Iron(II) Supported by a Bulky b-Diketiminate Ligand: Synthesis and Insertion of CO to give Square Pyramidal Complexes.”, Organometallics, 2002, 21, 4808-4814.

18

Hughes, R.P.; Smith, J.M.; Incarvito, C.D.; Lam, K.-C.; Rhatigan, B.; Rheingold, A.L. “Cationic Iridium-Perfluoroalkyl Complexes with NH3 and PH3 Ligands. Activation of Carbon-Fluorine Bonds by H2S to Give Bis(trifluoromethyl)dithiametallacyclobutane and Bis(trifluoromethyl)trithiametallacyclohexane Complexes.”, Organometallics, 2002, 21, 2136-2144.

17

Andres, H.; Bominaar, E.L.; Smith, J.M.; Eckert, N.A.; Holland, P.L.; Münck, E. “Planar Three-Coordinate High-Spin FeII Complexes with Large Orbital Angular Momentum: Mössbauer, Electron Paramagnetic Resonance, and Electronic Structure Studies.”, J. Am. Chem. Soc., 2002, 124, 3012-3025.

16

Smith, J.M.; Lachicotte, R.J.; Rogers, K.R.; Lukat-Rogers, G.; Pittard, K.A.; Cundari, T.R.; Holland, P.L. "Stepwise Reduction of Dinitrogen Bond Order by a Low Coordinate Iron Complex.", J. Am. Chem. Soc. 2001, 123, 9222-9223.

15

Smith, J.M.; Lachicotte, R.J.; Holland, P.L “Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex.”, Chem. Commun. 2001, 1542-1543.

14

Hughes, R.P.; Lindner, D.C.; Smith, J.M.; Zhang, D.; Incarvito, C.; Lam, K.-C.; Liable-Sands, L.M.; Sommer, R.; Rheingold, A.L. “Water, water, everywhere. Synthesis and structures of perfluoroalkyl rhodium and iridium(III) compounds containing water ligands.”, J. Chem. Soc., Dalton Trans. 2001, 2270-2278.

13

Hughes, R.P.; Kovacik, I.; Lindner, D.C.; Smith, J.M.; Willemsen, S.; Zhang, D.; Guzei, I.A.; Rheingold, A.L. “Unusual Reactivity of 'Proton Sponge' as a Hydride Donor to Transition Metals: Synthesis and Structural Characterization of Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III).”, Organometallics 2001, 20, 3190-3197.

12

Smith, J.M.; Coville, N.J. “Steric Parameters of Conformationally Flexible Ligands from X-ray Structural Data. 2. P(OR)3 Ligands in Multiple Ligand Environments.”, Organometallics 2001, 20, 1210-1215.

11

Grimmer, N.E.; Coville, N.J.; de Koning, C.B.; Smith, J.M.; Cook, L.M. “Zirconium bis-indenyl compounds. Synthesis and X-ray crystallography study of 1- and 2-substituted bis(R-indenyl)zirconium dichloride metallocenes.”, J. Organomet. Chem. 2000, 616, 112-127.

10

Smith J.M.; Coville, N.J.; Cook, L.M.; Boeyens, J.C.A. “Steric Parameters of Conformationally Flexible Ligands from X-ray Structural Data. 1. P(OR)3 Ligands in Equivalent Ligand Environments.”, Organometallics 2000, 19, 5273-5280.

9

Smith, J.M.; Cheng, L.; Schulte, J.; Dimpe, P.S.; Adsetts, M.S.; Coville, N.J.; Cook, L.M.; Boeyens, J.C.A.; Levendis, D.C. “Solid State Reactivity and Crystal Structure Studies. The Case of diag-lat Isomerization in [Re(h5-C5H4Me)(CO)(P(OPh)3)Br2] and [Re(h5-C5H4tBu)(CO)2Br2].”, Organometallics 2000, 19, 2597-2602.

8

Hughes, R.P.; Smith, J.M.; Liable-Sands, L.M.; Concolino, T.E.; Lam, K.-C.; Incarvito, C.; Rheingold, A.L. “Syntheses and X-ray crystallographic study of [Ir(h5-C5Me5)(L)(RF)I] (L = CO, PMe3; RF = CF2CF3, CF2CF2CF3, CF2C6F5, CF(CF3)2) complexes. Cone and solid angle steric parameters for perfluoroalkyl ligands.”, J. Chem. Soc., Dalton Trans. 2000, 873-879.

7

Hughes, R.P.; Smith, J.M. “Hydrogenolysis of Aliphatic Carbon-Fluorine Bonds in Fluoroalkyl-Iridium Complexes to Give Hydrofluorocarbons.”, J. Am. Chem. Soc. 1999, 121, 6084-6085. (featured in Chemtracts – Inorg. Chem. 2000, 13, 796-799.)

6

Taverner, B.C.; Smith, J.M.; White, D.P.; Coville, N.J. “Quantification of Ligand-Ligand Interactions using Solid Angles.”, S. Afr. J. Chem. 1997, 50, 59-66.

5

Smith, J.M.; Taverner, B.C.; Coville, N.J. “Cone Angle Radial Profiles.”, J. Organomet. Chem. 1997, 530, 131-140.

4

Smith, J.M.; Pelly, S.C.; Coville, N.J. “Intramolecular Steric Interactions in [h5-C5H3(SiMe3)2Ru(CO)(L)I] - Analysis by Radial Profiles.”, J. Organomet. Chem. 1996, 525, 159-166.

3

Smith, J.M.; Coville, N.J. “Analysis of Stereochemical Non-Rigidity in Five-Coordinate Cyclopentadienyl Complexes by the Structure Correlation Method.”, Organometallics 1996, 15, 3388-3392.

2

Smith, J.M.; White, D.; Coville, N.J. “Substituted Cyclopentadienyl Ligands 11. Intramolecular Steric Interactions in [(h 5-C5H4(SiMe3))Mo(CO)2(L)I].”, Bull. Chem. Soc. Ethiop. 1996, 10, 1-8.

1

Smith, J.M; White, D.P.; Coville, N.J. “Substituted Cyclopentadienyl Ligands 10. Intramolecular Steric Interactions in [(h 5-C5H3(SiMe3)2)Mo(CO)2(L)I].”, Polyhedron 1996, 15, 4541-4554.